Tert-Butyl Hydroperoxide

CAS# 75-91-2

Product Description

Tert-butyl hydroperoxide (TBHP) is a commonly used organic peroxide with a variety of industrial applications. 

Product:

Tert-Butyl Hydroperoxide

CAS:

75-91-2

Synonym:

1,1-Dimethylethyl hydroperoxide; 2-Hydroperoxy-2-methylpropane

Structure:

Typical Characteristics

Appearance

Colorless liquid

Boiling point

89 °C (decomposes)

Density

0.8960 g/cm3

Flash Point

43 °C

Melting point

-8 °C

Molecular Weight

90.12

Odor

Pungent odor

Purity

99%

Refractive index

1.4015

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We Offer Tert-Butyl Hydroperoxide
in various grades

A few of the grades available are listed below:

Tert-Butyl Hydroperoxide used in many
industry applications

Tert-butyl hydroperoxide (TBHP) is a commonly used organic peroxide with a variety of industrial applications. Here are some of its main uses:

  1. Initiator in Polymerization Reactions: TBHP is often employed as a radical initiator in the polymerization of various monomers, such as styrene, acrylics, and vinyl acetate. It helps initiate the polymerization process by generating free radicals, which propagate the polymer chain reaction.
  2. Oxidation Reactions: It serves as an oxidizing agent in organic synthesis reactions, facilitating the conversion of organic substrates to desired products. TBHP can oxidize alkenes to epoxides, alcohols to ketones or aldehydes, and sulfides to sulfoxides or sulfones.
  3. Manufacture of Fine Chemicals: TBHP is utilized in the production of various fine chemicals and pharmaceutical intermediates. It enables the synthesis of functionalized compounds with specific chemical properties and functionalities, which are valuable in the pharmaceutical, agrochemical, and specialty chemical industries.
  4. Desulfurization: In the petroleum industry, TBHP is employed for desulfurization processes, where it reacts with sulfur-containing compounds in crude oil or petroleum fractions to facilitate their removal. This helps in reducing sulfur content in fuels, meeting environmental regulations, and improving fuel quality.
  5. Epoxidation of Olefins: TBHP is commonly used in the epoxidation of olefins to produce epoxides, which are valuable intermediates in the synthesis of various chemicals, including plastics, resins, and adhesives. This reaction is particularly important in the manufacture of epoxy resins.
  6. Polymer Modification: TBHP is utilized in the modification of polymers to introduce functional groups or improve their properties. It can be employed in graft copolymerization reactions, crosslinking processes, or surface modification treatments to enhance polymer performance, such as thermal stability, chemical resistance, or adhesion.
  7. Chemical Safety: TBHP is also used as a chemical indicator or test reagent for detecting the presence of reducing agents or metal ions in chemical reactions. Its reaction with certain compounds produces visible color changes, indicating the occurrence of specific chemical reactions or the presence of impurities.
  8. Hydroxylation Reactions: TBHP can be employed in hydroxylation reactions to introduce hydroxyl groups (-OH) into organic molecules. This is useful in the synthesis of alcohols, phenols, and other oxygen-containing compounds, which have applications in pharmaceuticals, agrochemicals, and materials science.
  9. Waste Water Treatment: TBHP is sometimes used in waste water treatment processes as an oxidizing agent for the degradation of organic pollutants. It helps in the removal of organic contaminants from industrial effluents, contributing to environmental protection and water quality management.
  10. Textile and Pulp Bleaching: TBHP can be employed in textile bleaching processes, where it helps remove colorants and impurities from fabrics and fibers. It is also used in the pulp and paper industry for bleaching wood pulp, improving the brightness and quality of paper products.